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• W2053283514 endingPage "2069" @default.
• W2053283514 startingPage "2063" @default.
• W2053283514 abstract "Reactions of triarylsilanes such as HSiPh3, HSi(C6H4Me-p)3, HSi(C6H4OMe-p)3, HSi(C6H4Cl-p)3, HSi(C6H4F-p)3, and HSi(C6H4CF3-p)3 with RhClL2 (L = P(i-Pr)3) give a series of hydrido(triarylsilyl)rhodium(III) complexes, RhCl(H)(SiAr3)L2 (1, Ar = Ph; 2, Ar = C6H4Me-p; 3, Ar = C6H4OMe-p; 4, Ar = C6H4Cl-p; 5, Ar = C6H4F-p; 6, Ar = C6H4CF3-p). Tris(phenylethynyl)silane also reacts with the Rh(I) complex to give another oxidative-addition product, RhCl(H)[Si(C⋮CPh)3]L2 (7). X-ray analyses of 1 and 7 show a distorted-square-pyramidal coordination around the Rh center with the silyl ligand at the apical position. Prolonged reactions of HSiPh3 and of HSi(C6H4OCF3-p)3 with RhClL2 give dinuclear complexes, RhL(SiAr3)H(μ-Cl)(μ-H)RhH(SiAr3)L (8, Ar = Ph; 9, Ar = C6H4OCF3-p). X-ray crystallography of 9 shows a molecular structure containing two Rh centers bridged with hydrido and chloro ligands. 1,1,3,3-Tetraisopropyldisiloxane undergoes oxidative addition of the SiH bonds to RhClL2 to give a symmetric dinuclear Rh(III) complex with bridging hydrido, chloro, and disiloxanyl ligands, RhL(H)(μ-H)(μ-Cl)[μ-(i-Pr)2SiOSi-(i-Pr)2]Rh(H)L (10)." @default.
• W2053283514 created "2016-06-24" @default.
• W2053283514 creator A5037548640 @default.
• W2053283514 creator A5080828316 @default.
• W2053283514 creator A5088181080 @default.
• W2053283514 date "1997-05-01" @default.
• W2053283514 modified "2023-10-12" @default.
• W2053283514 title "A New Series of Mono- and Dinuclear Hydridosilylrhodium(III) Complexes, RhCl(H)(SiAr₃)L₂and RhL(SiAr₃)H(μ-Cl)(μ-H)RhH(SiAr₃)L (L = P(<i>i</i>-Pr₃)). Preparation by Oxidative Addition of HSiAr₃and Molecular Structures of the Complexes" @default.
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• W2053283514 doi "https://doi.org/10.1021/om961048h" @default.
• W2053283514 hasPublicationYear "1997" @default.
• W2053283514 type Work @default.

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