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• W2053334037 abstract "Abstract The electrochemical performance of NaFe 0.2 Ni 0.4 Ti 0.4 O 2 and NaFe 0.4 Ni 0.3 Ti 0.3 O 2 is studied in NaClO 4 and NaFSI based electrolytes for their potential use as cathodes in sodium-ion batteries. An initial discharge capacity of ∼120 mAh g −1 is observed for both the compositions at 12 mA g −1 in narrow voltage window of 3.75–2.60 V. The optimization of the upper cut-off voltage leads to a decrease of both the polarization and the irreversible capacity. NaFe 0.4 Ni 0.3 Ti 0.3 O 2 shows a smoother voltage profile than NaFe 0.2 Ni 0.4 Ti 0.4 O 2 with an average voltage ≥3.1 V. For NaFe 0.4 Ni 0.3 Ti 0.3 O 2 discharge capacity drops by 17% of its initial value using 1 M NaFSI in PC, whereas the cycling with 1 M NaClO 4 in PC lead to a decrease of 25% of its initial capacity after 30 cycles. Although the cycling stability of this compound is higher than that of NaFe 0.2 Ni 0.4 Ti 0.4 O 2 , the use of NaFSI improves the coulombic efficiency and cycle life for both cathode compositions compared to NaClO 4 ." @default.
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• W2053334037 date "2015-01-01" @default.
• W2053334037 modified "2023-10-17" @default.
• W2053334037 title "Electrochemical performance of NaFe (Ni0.5Ti0.5)1−O2 (x = 0.2 and x = 0.4) cathode for sodium-ion battery" @default.
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• W2053334037 doi "https://doi.org/10.1016/j.jpowsour.2014.09.050" @default.
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