Matches in SemOpenAlex for { <https://semopenalex.org/work/W2053344147> ?p ?o ?g. }
Showing items 1 to 87 of
87
with 100 items per page.
- W2053344147 abstract "Abstract An expression for the emf of an isothermal solid state bielectrolyte cell is developed starting from the basic equations of transport for each solid electrolyte. If the two different migrating species react to form a compound at well defined activity at the interface between the two solid electrolytes, interfacial chemical potentials and the emf are unambiguously defined. The interfacial chemical potentials are determined by the transport properties of the two solid electrolytes. The emf of the bielectrolyte cell will be less than that calculated from the Gibb's energy change for the virtual cell reaction when the interfacial or electrode chemical potentials lie outside the electrolytic conduction domain ( t ion >0.99) of the solid electrolytes. Using estimated values for electonic and hole conductivities in Na β-alumina, the emf of a bielectrolyte combination consisting of β-alumina and (CaO)ZrO 2 is computed for different chemical potentials of sodium and oxygen at the electrodes. The chemical potential gradient for sodium across β-alumina is found to be very small because the conductivity of β-alumina is much larger than that of (CaO)ZrO 2 . When two cationic or anionic conductors with different mobile species are coupled together, the chemical potentials at junction of the solid electrolytes and hence the emf are usually ill defined. A definite relationship between ionic fluxes in each electrolyte is necessary to mathematically define the interfacial chemical potentials." @default.
- W2053344147 created "2016-06-24" @default.
- W2053344147 creator A5000862593 @default.
- W2053344147 creator A5015001000 @default.
- W2053344147 date "1990-04-01" @default.
- W2053344147 modified "2023-09-23" @default.
- W2053344147 title "EMF of bielectrolyte solid state cells with different mobile ions in each phase" @default.
- W2053344147 cites W1963965403 @default.
- W2053344147 cites W2042554319 @default.
- W2053344147 doi "https://doi.org/10.1016/0013-4686(90)90016-s" @default.
- W2053344147 hasPublicationYear "1990" @default.
- W2053344147 type Work @default.
- W2053344147 sameAs 2053344147 @default.
- W2053344147 citedByCount "4" @default.
- W2053344147 countsByYear W20533441472017 @default.
- W2053344147 crossrefType "journal-article" @default.
- W2053344147 hasAuthorship W2053344147A5000862593 @default.
- W2053344147 hasAuthorship W2053344147A5015001000 @default.
- W2053344147 hasConcept C102264631 @default.
- W2053344147 hasConcept C109883240 @default.
- W2053344147 hasConcept C121332964 @default.
- W2053344147 hasConcept C127535462 @default.
- W2053344147 hasConcept C131540310 @default.
- W2053344147 hasConcept C133347239 @default.
- W2053344147 hasConcept C138679309 @default.
- W2053344147 hasConcept C145148216 @default.
- W2053344147 hasConcept C147789679 @default.
- W2053344147 hasConcept C17525397 @default.
- W2053344147 hasConcept C178790620 @default.
- W2053344147 hasConcept C179104552 @default.
- W2053344147 hasConcept C185592680 @default.
- W2053344147 hasConcept C2182769 @default.
- W2053344147 hasConcept C37463463 @default.
- W2053344147 hasConcept C44280652 @default.
- W2053344147 hasConcept C537181965 @default.
- W2053344147 hasConcept C62520636 @default.
- W2053344147 hasConcept C68801617 @default.
- W2053344147 hasConcept C85434573 @default.
- W2053344147 hasConcept C97355855 @default.
- W2053344147 hasConceptScore W2053344147C102264631 @default.
- W2053344147 hasConceptScore W2053344147C109883240 @default.
- W2053344147 hasConceptScore W2053344147C121332964 @default.
- W2053344147 hasConceptScore W2053344147C127535462 @default.
- W2053344147 hasConceptScore W2053344147C131540310 @default.
- W2053344147 hasConceptScore W2053344147C133347239 @default.
- W2053344147 hasConceptScore W2053344147C138679309 @default.
- W2053344147 hasConceptScore W2053344147C145148216 @default.
- W2053344147 hasConceptScore W2053344147C147789679 @default.
- W2053344147 hasConceptScore W2053344147C17525397 @default.
- W2053344147 hasConceptScore W2053344147C178790620 @default.
- W2053344147 hasConceptScore W2053344147C179104552 @default.
- W2053344147 hasConceptScore W2053344147C185592680 @default.
- W2053344147 hasConceptScore W2053344147C2182769 @default.
- W2053344147 hasConceptScore W2053344147C37463463 @default.
- W2053344147 hasConceptScore W2053344147C44280652 @default.
- W2053344147 hasConceptScore W2053344147C537181965 @default.
- W2053344147 hasConceptScore W2053344147C62520636 @default.
- W2053344147 hasConceptScore W2053344147C68801617 @default.
- W2053344147 hasConceptScore W2053344147C85434573 @default.
- W2053344147 hasConceptScore W2053344147C97355855 @default.
- W2053344147 hasLocation W20533441471 @default.
- W2053344147 hasOpenAccess W2053344147 @default.
- W2053344147 hasPrimaryLocation W20533441471 @default.
- W2053344147 hasRelatedWork W1493273914 @default.
- W2053344147 hasRelatedWork W1578622113 @default.
- W2053344147 hasRelatedWork W1640033178 @default.
- W2053344147 hasRelatedWork W1774625702 @default.
- W2053344147 hasRelatedWork W1927687779 @default.
- W2053344147 hasRelatedWork W1991650467 @default.
- W2053344147 hasRelatedWork W2011776201 @default.
- W2053344147 hasRelatedWork W2018443544 @default.
- W2053344147 hasRelatedWork W2020484037 @default.
- W2053344147 hasRelatedWork W2035196241 @default.
- W2053344147 hasRelatedWork W2071084838 @default.
- W2053344147 hasRelatedWork W2072948144 @default.
- W2053344147 hasRelatedWork W2082361314 @default.
- W2053344147 hasRelatedWork W2090343316 @default.
- W2053344147 hasRelatedWork W2090588878 @default.
- W2053344147 hasRelatedWork W2122821801 @default.
- W2053344147 hasRelatedWork W215819308 @default.
- W2053344147 hasRelatedWork W2490245727 @default.
- W2053344147 hasRelatedWork W2520441650 @default.
- W2053344147 hasRelatedWork W2530306773 @default.
- W2053344147 isParatext "false" @default.
- W2053344147 isRetracted "false" @default.
- W2053344147 magId "2053344147" @default.
- W2053344147 workType "article" @default.