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• W2053361448 endingPage "277" @default.
• W2053361448 startingPage "253" @default.
• W2053361448 abstract "The thermal behaviour of hydrochlorides of esters (mostly methyl esters) of several naturally occurring 2-amino acids was examined by thermoanalytical methods (DTA, TG, DTG). Heating of the compounds at a constant rate up to 750 K leads to their total or partial volatilization and formation, in the latter case, of a non-volatile residue comprising a mixture of carbonization products. The thermodynamics of the thermal decomposition of the compounds studied was analysed by considering several possible pathways for primary processes. The thermochemical characteristics necessary for these considerations, such as the enthalpies of formation of gaseous 2-amino acid esters and of their crystalline hydrochlorides, were estimated on the basis of the Benson group additivity method and available literature information. Using characteristics thus derived and other data from the literature, the enthalpies of primary processes were evaluated, as well as volatilization temperatures of some of the reaction products. The MINDO/3, MNDO and AMI quantum chemistry methods were applied to evaluate several physicochemical characteristics, in the gaseous phase, for glycine and L-alanine methyl esters and glycine ethyl ester, and also for their protonated forms and decomposition fragments. The thermodynamics of the thermal decomposition of the three above mentioned compounds was then examined using the thermochemical characteristics for gaseous reactants derived by MINDO/3, MNDO and AMI. The AMI method was also applied to analyse structure and energetics of the transition state (saddle point structure) for the decarboxylation of glycine methyl ester. Further, the electrostatic energy of the hydrochloride of L-proline phenylmethyl ester was derived on the basis of the Ewald method and the known crystal structure of the compound. This quantity has been compared with values of crystal lattice energy of hydrochlorides of several other amino acid esters estimated on the basis of the thermochemical cycle using available literature information and the heats of formation of gaseous amino acid esters and their monocations evaluated by quantum chemistry methods." @default.
• W2053361448 created "2016-06-24" @default.
• W2053361448 creator A5025797603 @default.
• W2053361448 creator A5029877184 @default.
• W2053361448 creator A5055555639 @default.
• W2053361448 creator A5058691299 @default.
• W2053361448 creator A5074584392 @default.
• W2053361448 date "1990-11-01" @default.
• W2053361448 modified "2023-10-16" @default.
• W2053361448 title "Thermal properties, crystal lattice energy, mechanism and energetics of the thermal decomposition of hydrochlorides of 2-amino acid esters" @default.
• W2053361448 cites W1495889551 @default.
• W2053361448 cites W1498464774 @default.
• W2053361448 cites W1500641927 @default.
• W2053361448 cites W1523586838 @default.
• W2053361448 cites W1567859324 @default.
• W2053361448 cites W1603903629 @default.
• W2053361448 cites W1895654207 @default.
• W2053361448 cites W1944134883 @default.
• W2053361448 cites W1964495182 @default.
• W2053361448 cites W1965822707 @default.
• W2053361448 cites W1966238363 @default.
• W2053361448 cites W1974236296 @default.
• W2053361448 cites W1974419441 @default.
• W2053361448 cites W1976085322 @default.
• W2053361448 cites W1976106600 @default.
• W2053361448 cites W1978438141 @default.
• W2053361448 cites W1982094813 @default.
• W2053361448 cites W1982302837 @default.
• W2053361448 cites W1988237918 @default.
• W2053361448 cites W1990486961 @default.
• W2053361448 cites W1991629012 @default.
• W2053361448 cites W1993748537 @default.
• W2053361448 cites W1998200259 @default.
• W2053361448 cites W2000084229 @default.
• W2053361448 cites W2001276002 @default.
• W2053361448 cites W2001676859 @default.
• W2053361448 cites W2002557662 @default.
• W2053361448 cites W2004161503 @default.
• W2053361448 cites W2004547806 @default.
• W2053361448 cites W2006873566 @default.
• W2053361448 cites W2006930438 @default.
• W2053361448 cites W2007508017 @default.
• W2053361448 cites W2014910720 @default.
• W2053361448 cites W2016761184 @default.
• W2053361448 cites W2018948023 @default.
• W2053361448 cites W2019117629 @default.
• W2053361448 cites W2028232415 @default.
• W2053361448 cites W2029701326 @default.
• W2053361448 cites W2029961090 @default.
• W2053361448 cites W2031392947 @default.
• W2053361448 cites W2037039818 @default.
• W2053361448 cites W2037454838 @default.
• W2053361448 cites W2041245710 @default.
• W2053361448 cites W2041965814 @default.
• W2053361448 cites W2044302451 @default.
• W2053361448 cites W2047278974 @default.
• W2053361448 cites W2047642059 @default.
• W2053361448 cites W2048055436 @default.
• W2053361448 cites W2051066010 @default.
• W2053361448 cites W2058880519 @default.
• W2053361448 cites W2058946310 @default.
• W2053361448 cites W2059404117 @default.
• W2053361448 cites W2060174226 @default.
• W2053361448 cites W2060334548 @default.
• W2053361448 cites W2071613083 @default.
• W2053361448 cites W2073246783 @default.
• W2053361448 cites W2077973224 @default.
• W2053361448 cites W2084925932 @default.
• W2053361448 cites W2086124825 @default.
• W2053361448 cites W2087138441 @default.
• W2053361448 cites W2092520930 @default.
• W2053361448 cites W2094732000 @default.
• W2053361448 cites W2095267507 @default.
• W2053361448 cites W2108326572 @default.
• W2053361448 cites W2108406664 @default.
• W2053361448 cites W2123428946 @default.
• W2053361448 cites W2135625467 @default.
• W2053361448 cites W2138506897 @default.
• W2053361448 cites W2151654100 @default.
• W2053361448 cites W2157776156 @default.
• W2053361448 cites W2158577259 @default.
• W2053361448 cites W2158628418 @default.
• W2053361448 cites W2193361705 @default.
• W2053361448 cites W2241240002 @default.
• W2053361448 cites W2312658258 @default.
• W2053361448 cites W2313803630 @default.
• W2053361448 cites W2317428995 @default.
• W2053361448 cites W2320231981 @default.
• W2053361448 cites W2323506805 @default.
• W2053361448 cites W2323951023 @default.
• W2053361448 cites W2324156159 @default.
• W2053361448 cites W2332138458 @default.
• W2053361448 cites W2398279716 @default.
• W2053361448 cites W2412194237 @default.
• W2053361448 cites W2522295976 @default.
• W2053361448 cites W2798662629 @default.
• W2053361448 cites W2949232466 @default.
• W2053361448 cites W3004491577 @default.

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