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• W2053385487 startingPage "967" @default.
• W2053385487 abstract "The effect of pressure on the association of rhodamine B (RB) and methylene blue (MB) in water has been investigated on the basis of their absorption spectra under hydrostatic pressures up to 4500 atm at room temperatures. Pressure increases the association of these dyes. The volume changes accompanying the 2 monomerightleftarrowsdimer process are calculated. The values are −10.4 cc/mol and −10.6 cc/mol in RB and MB respectively. These negative values are inconsistent with the suggestions by Rohatgi and Singhal and by Mukerjee and Ghosh that hydrophobic bonds are responsible for the associations of RB and MB. It is more plausible to assume that the hydrogen bond is the main binding force in the dye associations. London’s dispersion force and the increase in the dielectric constant of water with the increase in the pressure may also assist the dye associations." @default.
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• W2053385487 date "1971-04-01" @default.
• W2053385487 modified "2023-09-25" @default.
• W2053385487 title "The Effect of Pressure on the Association of Dye Molecules in an Aqueous Solution" @default.
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• W2053385487 doi "https://doi.org/10.1246/bcsj.44.967" @default.
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