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- W2053442998 abstract "The asymmetric unit of the title compound, (C25H22P)2-[Ni(C4N2S2)2] or (BzTPP)2[Ni(mnt)2] (where BzTPP is 1-benzyltriphenylphosphonium and mnt is maleonitriledithiolate), consists of one (BzTPP)+ cation and one-half of a centrosymmetric [Ni(mnt)2]2− anion. The NiII atom of the anion is coordinated by four S atoms from two mnt2− ligands and exhibits the expected square-planar coordination geometry. The (BzTPP)+ cation adopts a conformation where the four phenyl rings are twisted with respect to the plane of the P—C—C chain that links them. Weak C—H⋯N and C—H⋯π interactions are present in the crystal structure." @default.
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- W2053442998 date "2007-04-25" @default.
- W2053442998 modified "2023-10-16" @default.
- W2053442998 title "Bis(benzyltriphenylphosphonium) bis(1,2-dicyanoethene-1,2-dithiolato)nickel(II)" @default.
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- W2053442998 doi "https://doi.org/10.1107/s1600536807018715" @default.
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