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- W2053443721 abstract "Abstract Photolysis of [FeCp(C 6 H 5 CH 3 )] + PF 6 − ( 1 + ), (Cp = η 5 -C 5 H 5 ) with visible light in acetonitrile in the presence of 1 equiv. dppm gives [FeCp(η 2 -dppm)(CH 3 CN)] + -PF 6 − ( 2 + ) (dppm = 1,2-bis(diphenylphosphino)methane) and photolysis in dichloromethane in the presence of 1 equiv. dppm gives [FeCp(η 2 -dppm)(η 1 -dppm)] + PF 6 − ( 3 + ). Complex 3 + is converted into 2 + in acetonitrile upon reflux or irradiation. Complex 2 + reacts under 5–10 atm of CO at 20°C in acetone in the dark to give [FeCp(dppm)(CO)] + PF 6 − ( 4 + ), which upon irradiation with visible light in acetonitrile is reconverted into 2 + . The 2 + / 4 + pair is a photochromic system. Complex 2 + is reversibly oxidized (cyclic voltammetry) and complex 4 + is irreversibly reduced (1 F) at an Hg cathodic pool or Na/Hg to give [{FeCp(μ 2 -CO)} 2 (μ 2 -dppm)] ( 5 ). The efficient photolytic and electrocatalytic exchanges of arene by P donors in 1 + are compared. The crystal structures of 2 + and 4 + (as their PF 6 − salts) are reported." @default.
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- W2053443721 date "1989-11-01" @default.
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- W2053443721 title "Synthesis, redox properties, and crystal structures of the diphenylphosphinomethaneiron(II) complexes [FeCp(dppm)(L)]+PF6− (L = CO and CH3CN)" @default.
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- W2053443721 doi "https://doi.org/10.1016/0022-328x(89)80093-2" @default.
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