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• W2053443861 abstract "A new offset analogue of the classical [Mn6O2]-core oxime-bridged single-molecule magnets is introduced with a modified stacking arrangement of the [Mn3O] units. Studies of the magnetic properties reveal antiferromagnetic exchange interactions, a spin S = 4 ground state and population of low-lying excited states. Slow relaxation of the magnetization can be detected, with a corresponding energy barrier of 35.8 K. Interpretation of these features is supported with high-frequency EPR studies, quantifying the easy-axis type magnetic anisotropy, leading to a biaxial system. Redox properties investigated by cyclic and differential pulse voltammetry reveal multiple irreversible redox processes." @default.
• W2053443861 created "2016-06-24" @default.
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• W2053443861 date "2015-01-26" @default.
• W2053443861 modified "2023-10-01" @default.
• W2053443861 title "A New “Offset” Analogue of the Classical Oxime-Bridged [Mn^III₆] Single-Molecule Magnets" @default.
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• W2053443861 doi "https://doi.org/10.1021/ic502787q" @default.
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• W2053443861 hasPublicationYear "2015" @default.
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