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- W2053444990 abstract "By means of plasma polymerization, thin layers of polysiloxanes (octamethylcyclotetrasiloxane (OMTS), hexamethyldisiloxane (HMDSO)) were deposited onto single-crystal quartz resonators with frequency of oscillation 5 MHz, and the amount of adsorbed vapour, which is proportional to the volume concentration, was determined from the change in frequency. The best results were obtained with OMTS(CH3)8Si4O4 polymerized in r.f. discharge plasma (27 MHz). Selective sorption of inhalating anaesthetics was achieved by annealing quartz resonators covered by poly-OMTS at 100–200 °C. The measurement was carried out in a dynamic regime in such a way that the vapour of the substance measured was brought to the resonators by carrier gas (air, N2, N2O). The concentration of vapour of the substance measured in the carrier gas varied from 0.25 to 5.0 vol.%, and in H2O vapour from 1% to 90%. To obtain the maximum sensitivity to the anaesthetic, minimum sensitivity to H2O vapour and shortest possible detection time, the functional layer of OMTS was treated. This technique, together with the selection of optimum parameters during layer deposition (layer thickness, rate of deposition, etc.), resulted in the required parameters being achieved. The designed system can be applied in practice in anaesthesiology." @default.
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- W2053444990 date "1992-09-01" @default.
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- W2053444990 title "Selective gas sorption of plasma-polymerized organosiloxane thin films" @default.
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- W2053444990 doi "https://doi.org/10.1016/0040-6090(92)90843-z" @default.
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