Matches in SemOpenAlex for { <https://semopenalex.org/work/W2053449852> ?p ?o ?g. }
- W2053449852 endingPage "2141" @default.
- W2053449852 startingPage "2130" @default.
- W2053449852 abstract "Abstract Well‐defined peptide‐poly(ε‐caprolactone) (Pep‐PCL) biohybrids were successfully synthesized by grafting‐from ring‐opening polymerization (ROP) of ε‐caprolactone (CL) using designed amine‐terminated sequence‐defined peptides as macroinitiators. MALDI‐TOF‐MS and 1 H NMR analyses confirmed the successful attachment of peptide to the PCL chain. The gel permeation chromatography (GPC) measurement showed that the Pep‐PCL biohybrids with controllable molecular weights and low polydispersities (PDI <1.5) were obtained by this approach. The aggregation of Pep‐PCL hybrid molecules in THF solution resulted in the formation of micro/nanospheres as confirmed through FESEM, TEM, and DLS analyses. The circular dichroism study revealed that the secondary structure of peptide moiety was changed in the peptide‐PCL biohybrids. The crystallization and melting behavior of Pep‐PCL hybrids were somewhat changed compared with that of neat PCL of comparable molecular weight as revealed by DSC and XRD measurements. In Pep‐PCL biohybrids, extinction rings were observed in the PCL spherulites, in contrast with the normal spherulite morphology of the neat PCL. There was a substantial decrease (4–5 folds) in the spherulitic growth rate after the incorporation of peptide moiety at the end of PCL chain as measured by polarizing optical microscopy. Pseudomonas lipase catalyzed enzymatic degradation was studied for Pep‐PCL hybrids and neat PCL. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012" @default.
- W2053449852 created "2016-06-24" @default.
- W2053449852 creator A5017659760 @default.
- W2053449852 creator A5017933441 @default.
- W2053449852 creator A5089270775 @default.
- W2053449852 date "2012-02-28" @default.
- W2053449852 modified "2023-10-18" @default.
- W2053449852 title "Peptide-poly(ε-caprolactone) biohybrids by grafting-from ring-opening polymerization: Synthesis, aggregation, and crystalline properties" @default.
- W2053449852 cites W1701833909 @default.
- W2053449852 cites W1966253398 @default.
- W2053449852 cites W1966432607 @default.
- W2053449852 cites W1967314908 @default.
- W2053449852 cites W1968640798 @default.
- W2053449852 cites W1978300654 @default.
- W2053449852 cites W1983999269 @default.
- W2053449852 cites W1988510823 @default.
- W2053449852 cites W1990829567 @default.
- W2053449852 cites W1992013452 @default.
- W2053449852 cites W1999917843 @default.
- W2053449852 cites W2000730892 @default.
- W2053449852 cites W2008150408 @default.
- W2053449852 cites W2009283113 @default.
- W2053449852 cites W2013947518 @default.
- W2053449852 cites W2015888611 @default.
- W2053449852 cites W2016374704 @default.
- W2053449852 cites W2017624562 @default.
- W2053449852 cites W2017866595 @default.
- W2053449852 cites W2021120142 @default.
- W2053449852 cites W2021138079 @default.
- W2053449852 cites W2021983004 @default.
- W2053449852 cites W2023271298 @default.
- W2053449852 cites W2025257074 @default.
- W2053449852 cites W2026727321 @default.
- W2053449852 cites W2030855909 @default.
- W2053449852 cites W2032049827 @default.
- W2053449852 cites W2034822897 @default.
- W2053449852 cites W2037072498 @default.
- W2053449852 cites W2037221754 @default.
- W2053449852 cites W2040221748 @default.
- W2053449852 cites W2043466322 @default.
- W2053449852 cites W2048416285 @default.
- W2053449852 cites W2049930363 @default.
- W2053449852 cites W2051074688 @default.
- W2053449852 cites W2055393399 @default.
- W2053449852 cites W2058879685 @default.
- W2053449852 cites W2062219880 @default.
- W2053449852 cites W2063008630 @default.
- W2053449852 cites W2067017306 @default.
- W2053449852 cites W2069657045 @default.
- W2053449852 cites W2078499610 @default.
- W2053449852 cites W2081748357 @default.
- W2053449852 cites W2084419504 @default.
- W2053449852 cites W2084727844 @default.
- W2053449852 cites W2087253613 @default.
- W2053449852 cites W2093977698 @default.
- W2053449852 cites W2094342787 @default.
- W2053449852 cites W2094398474 @default.
- W2053449852 cites W2100046372 @default.
- W2053449852 cites W2112650492 @default.
- W2053449852 cites W2119968059 @default.
- W2053449852 cites W2120915183 @default.
- W2053449852 cites W2140973330 @default.
- W2053449852 cites W2145246634 @default.
- W2053449852 cites W2155601061 @default.
- W2053449852 cites W2156604584 @default.
- W2053449852 cites W2158396751 @default.
- W2053449852 cites W2159928256 @default.
- W2053449852 cites W2170916169 @default.
- W2053449852 cites W2171317808 @default.
- W2053449852 cites W2171383989 @default.
- W2053449852 cites W2335693270 @default.
- W2053449852 cites W39236032 @default.
- W2053449852 cites W4213162680 @default.
- W2053449852 cites W4243966276 @default.
- W2053449852 doi "https://doi.org/10.1002/pola.26003" @default.
- W2053449852 hasPublicationYear "2012" @default.
- W2053449852 type Work @default.
- W2053449852 sameAs 2053449852 @default.
- W2053449852 citedByCount "15" @default.
- W2053449852 countsByYear W20534498522013 @default.
- W2053449852 countsByYear W20534498522014 @default.
- W2053449852 countsByYear W20534498522015 @default.
- W2053449852 countsByYear W20534498522016 @default.
- W2053449852 countsByYear W20534498522017 @default.
- W2053449852 countsByYear W20534498522018 @default.
- W2053449852 countsByYear W20534498522019 @default.
- W2053449852 countsByYear W20534498522022 @default.
- W2053449852 crossrefType "journal-article" @default.
- W2053449852 hasAuthorship W2053449852A5017659760 @default.
- W2053449852 hasAuthorship W2053449852A5017933441 @default.
- W2053449852 hasAuthorship W2053449852A5089270775 @default.
- W2053449852 hasConcept C178790620 @default.
- W2053449852 hasConcept C185592680 @default.
- W2053449852 hasConcept C188027245 @default.
- W2053449852 hasConcept C203036418 @default.
- W2053449852 hasConcept C203897987 @default.
- W2053449852 hasConcept C2775937945 @default.
- W2053449852 hasConcept C2776568683 @default.