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- W2053460440 abstract "Die Ramanspektren des geschmolzenen und des dampfförmigen Selendioxids sind sehr ähnlich. Die Bandenzahl deutet auf ein temperaturabhängiges Gleichgewicht zwischen monomerem und dimerem Selendioxid sowohl in der Schmelze als auch im Dampf hin. Polymere Ketten, wie beim kristallinen Selendioxid, sind nicht nachweisbar. Für das Dimere erscheint uns ein sauerstoffverbrückter ebener Viererring am wahrscheinlichsten. Hierbei weisen Linienverbreiterungen und zwei intensive, polarisierte Banden bei ν = 955/966 cm−1 auf ein Gleichgewicht von trans- (C2h) mit der cis-Form (C2v) hin. About the Structure of Molten Selenium Dioxide The Raman spectra of molten and gaseous selenium dioxide are nearly identical. The number of bands indicates the existence of a temperature depending equilibrium of monomeric and dimeric selenium dioxide in the molten and the gaseous state. A chain structure as in the crystal could not be found. An oxygen-bridged planar ring seems most likely for the structure of the dimer. Broadening of bands two intense, polarized lines at ν = 955/966 cm−1 indicate an equilibrium of the trans-(C2h) with the cis-structure (C2v)." @default.
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- W2053460440 date "1975-09-01" @default.
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- W2053460440 title "�ber die Struktur von geschmolzenem Selendioxid" @default.
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- W2053460440 doi "https://doi.org/10.1002/zaac.19754160319" @default.
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