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• W2053469910 abstract "Here, we investigate p-type and n-type porous silicon (PS) reactivity towards oxygen and ammonia in the gas phase. We show that in both the environments, a clear correlation exists between the reaction rate and the confinement energy. In the frame of Marcus theory and starting from basic assumptions, a theoretical model has been developed correlating the charge transfer mechanism to the confinement size. The model well explains the experimental findings, predicting, moreover, the existence of a resonance in the reaction rate, function of the confinement energy." @default.
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• W2053469910 date "2005-11-01" @default.
• W2053469910 modified "2023-10-01" @default.
• W2053469910 title "Nanostructure reactivity: Confinement energy and charge transfer in porous silicon" @default.
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• W2053469910 doi "https://doi.org/10.1016/j.snb.2005.07.005" @default.
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