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- W2053532885 abstract "The electron spin resonance spectra of single crystals of manganese(II)-doped zinc maleate tetrahydrate have been investigated at room temperature. The transitions arise from a single type of site with gxx= 2.010, gyy= 1.992, and gzz= 2.035. The g shifts from the free spin value have been attributed to an electron-transfer process from the ligands to the S state ion. The observed angular variation of the allowed hyperfine transitions is in good agreement with theory. The spin-Hamiltonian parameters D= 360.5 × 10–4, E= 66.8 × 10–4, a=–8.9 × 10–4, and A=–87.0 × 10–4 cm–1 have been deduced. From the A value an ionicity of 96.5% is derived for the metal–ligand bonding. The analysis of forbidden hyperfine transitions leads to Q′= 1.58 × 10–4 and Q″= 0.28 × 10–4 cm–1 for the axial and rhombic components of the quadrupole coupling tensor respectively for the 55Mn nucleus." @default.
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- W2053532885 date "1988-01-01" @default.
- W2053532885 modified "2023-09-27" @default.
- W2053532885 title "A single-crystal electron spin resonance study of manganese(II)-doped zinc maleate tetrahydrate" @default.
- W2053532885 doi "https://doi.org/10.1039/dt9880000983" @default.
- W2053532885 hasPublicationYear "1988" @default.
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