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- W2053584387 abstract "Rate constants for the proton transfer reaction from Fischer thiocarbene complexes (CO)5MC(SR1)CH3 (M = Cr or W; R1 = n-butyl, isopropyl, tert-butyl, cyclohexyl) to OH– and various primary and secondary amines were determined in 50% acetonitrile–50% water at 25 °C. These measurements allowed the determination of the thermodynamic and kinetic acidities for these substrates. The results obtained show that there is a slight effect of the substituent on the thermodynamic acidity, which is governed by its hydrophobicity; whereas the effect on the kinetic acidity is more noticeable and is due to the steric effect of the substituent." @default.
- W2053584387 created "2016-06-24" @default.
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- W2053584387 date "2008-01-01" @default.
- W2053584387 modified "2023-09-30" @default.
- W2053584387 title "Effects of the alkyl substituent in the π-donor heteroatom on the kinetic and thermodynamic acidities of Fischer thiocarbene complexes" @default.
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- W2053584387 cites W1985870514 @default.
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- W2053584387 cites W1993009611 @default.
- W2053584387 cites W1993740251 @default.
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- W2053584387 cites W2003366477 @default.
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- W2053584387 cites W2009955424 @default.
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- W2053584387 doi "https://doi.org/10.1039/b709504j" @default.
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