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- W2053610756 abstract "Tellurite-based glasses of the chemical formula xLa 2 O 3 -(100 – x) TeO 2 , (2.5 ≤ x ≤ 12.5 mol%) have been prepared and studied by FTIR spectroscopy and the ultrasonic technique. The FTIR analysis indicated that La 2 O 3 transformed the TeO 3 into TeO 4 structural units in the range 2.5 ≤ x ≤ 5, while in the range 5 ≤ x ≤ 7.5 mol%; there is a coordination transformation of Te atoms in [TeO 4 ] groups into [Formula: see text] groups associated with the formation of non-bridging oxygens. Beyond x = 7.5 mol%, the structural units [Formula: see text] (tp) were destroyed and transformed into TeO 4 structural units that acted as a former and tightened the tellurite glass network more. The stretching force constant of the tellurite structural units was affected with the increase of La 2 O 3 content. The structural variations of the structural units of TeO 2 and La 2 O 3 affected the increase of density, the behaviour of the ultrasonic velocities, the elastic moduli, and both of the optical and acoustical Debye temperature with increasing La 2 O 3 content. The ratio of optical to acoustic Debye temperature represented the three-dimensional nature of tellurite-based glasses." @default.
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- W2053610756 date "2015-04-01" @default.
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- W2053610756 title "Structural and mechanical features of some lanthanum tellurite glasses" @default.
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- W2053610756 doi "https://doi.org/10.1139/cjp-2014-0044" @default.
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