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• W2053639544 abstract "Binding behaviors of two cucurbit[n]urils (CB[n]) hosts with the [CH3bpy(CH2)6bpyCH3]4+ (bpy = 4,4'-bipyridinium) guest were investigated by 1H NMR and MALDI-TOF-MS experiments. While the CB[6] and CB[7] form [2]pseudorotaxanes with the host located over the hexamethylene chain of the guest, only the CB[7] forms a [3]pseudorotaxane with both host molecules residing over the bipyridinium groups. The initial CB[7] host vacates the inclusion of the hexamethylene chain as a result of the electrostatic and steric repulsions that would arise in simultaneous binding of adjacent aliphatic and aromatic portions of the guest." @default.
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• W2053639544 date "2007-05-16" @default.
• W2053639544 modified "2023-10-08" @default.
• W2053639544 title "Binding Modes of Cucurbit[6]uril and Cucurbit[7]uril with a Tetracationic Bis(viologen) Guest" @default.
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• W2053639544 doi "https://doi.org/10.1021/jo070358e" @default.
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