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- W2053650153 abstract "Rhodium complexes with chiral chelating bis aminophosphines R*N (PPh2)CH2CH2(PPh2)NR* (R* S()α-methylbenzyl, ()menthyl) catalyze the asymmetric hydrogenation of prochiral olefinic precursors of α-aminoacids with good stereoselectivity (70 - 93%). It is noteworthy that the catalysts prepared starting from the corresponding monodentate ligands (i.e., R*N(PPh2)CH3) are ineffective in terms of asymmetric induction." @default.
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- W2053650153 date "1978-06-01" @default.
- W2053650153 modified "2023-09-27" @default.
- W2053650153 title "Chiral aminophosphine—rhodium complexes as catalysts for asymmetric hydrogenation of olefins" @default.
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- W2053650153 doi "https://doi.org/10.1016/0304-5102(78)80005-4" @default.
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