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- W2053670048 abstract "Single crystals of the title compound, trilead(II) bis-[tellurate(IV)] dibromide, have been grown under hydro-thermal conditions. The structure is isotypic with that of the chloride analogue, Pb(3)Te(2)O(6)Cl(2), and consists of three Pb, two Te, two Br and four O atoms in the asymmetric unit. Except for two of the O atoms, all atoms are located on mirror planes. The Pb(3)Te(2)O(6)Br(2) structure can be described as being built up from (∞) (2)[Pb(3)Te(2)O(6)](2+) layers extending parallel to (20) and Br(-) anions between the layers. Cohesion of the structure is accomplished through Pb-Br contacts of two of the three lead atoms, leading to highly asymmetric coordination polyhedra. The lone-pair electrons of both Te(IV) and Pb(II) atoms are stereochemically active and point towards the anionic halide layers." @default.
- W2053670048 created "2016-06-24" @default.
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- W2053670048 date "2010-01-16" @default.
- W2053670048 modified "2023-10-09" @default.
- W2053670048 title "Pb<sub>3</sub>Te<sub>2</sub>O<sub>6</sub>Br<sub>2</sub>" @default.
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- W2053670048 doi "https://doi.org/10.1107/s1600536809053604" @default.
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