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• W2053727011 abstract "Abstract Polypyrrole modified electrode prepared by electropolymerization of pyrrole in the presence of a complexing ligand, benzo-15-crown-5 (B15C5), was prepared and investigated as a La3+-selective electrode in acetonitrile. The potentiometric response of the electrode was linear within the La3+ concentration range 1 × 10−4 to 1 × 10−1 M with a Nernstian slope of 19.5 mV decade−1 in AN. The electrode was applied to study the complexation of the lanthanum (III) ion in acetonitrile with other basic solvent molecules (D) such as dimethyl sulfoxide, N,N-dimethylformamide, propylene carbonate, N,N,Diethylaniline and methanol. The successive complex formation constant (βi) and Gibbs energies of transfer (ΔGtr) of La3+ in AN in relation to such D were obtained." @default.
• W2053727011 created "2016-06-24" @default.
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• W2053727011 date "2017-02-01" @default.
• W2053727011 modified "2023-09-27" @default.
• W2053727011 title "A PPy-B15C5 modified lanthanum (III) electrode in acetonitrile and its thermodynamic application" @default.
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• W2053727011 doi "https://doi.org/10.1016/j.arabjc.2013.04.019" @default.
• W2053727011 hasPublicationYear "2017" @default.
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