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- W2053765145 abstract "It is shown that the low energy (λ > 3000 Å) photolysis of cis-HNSO in an argon matrix leads to formation of trans-HNSO. Four i.r. absorptions are observed and assigned for trans-HNSO and an approximate partial force field is calculated using data from isotopic substitutions. A comparison is made of the i.r. spectra of cis- and trans-HNSO using the intramolecular hydrogen bond of the cis form as a basis for explanation of the differences. Photolysis of cis-HNSO in argon matrices using vacuum u.v. light (1216 Å) has resulted in a single i.r. absorption at 1195 cm −1 which has been assigned to the radical, NSO." @default.
- W2053765145 created "2016-06-24" @default.
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- W2053765145 date "1975-08-01" @default.
- W2053765145 modified "2023-09-25" @default.
- W2053765145 title "The Photolysis of Matrix Isolated <i>cis</i>-Thionylimide. 2. The Identification and Infrared Spectra of <i>trans</i>-HNSO and NSO" @default.
- W2053765145 doi "https://doi.org/10.1139/v75-326" @default.
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