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• W2053798825 endingPage "1981" @default.
• W2053798825 startingPage "1977" @default.
• W2053798825 abstract "The pentafluorosulfanylacetic acid, HOOCCH2SF5, is dehydrated to the ketene OCCHSF5. Besides other more typical reactions this ketene isomerizes to the alkylidenesulfur tetrafluoride OFCCHSF4 which is hydrolyzed to the title compound OFCCHSF2O. This first alkylidenesulfur difluoride oxide exists in three, possibly four different isomeric structures at low temperatures, as was determined by NMR techniques. This is a result of hindered rotation of the CS and CC bonds. Strukturelle Dynamik des ersten Alkylidenschwefeldifluoridoxids Pentafluorsulfanylessigsäure, HOOCCH2SF5, läßt sich zum Keten OCCHSF5 entwässern. Dieses zeigt typische Reaktionen, aber es isomerisiert auch zum Alkylidenschwefeltetrafluorid, OFC–CHSF4, welches vorsichtig zur Titelverbindung OFCCHSF2O hydrolysiert werden kann. Dieses erste Alkylidenschwefeldifluoridoxid hat bei tiefen Temperaturen drei, vielleicht sogar vier verschiedene isomere Strukturen, wie mit der NMR-Spektroskopie gezeigt wird. Gehinderte Rotation der CS- und CC-Bindung wird für die Isomerie verantwortlich gemacht." @default.
• W2053798825 created "2016-06-24" @default.
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• W2053798825 date "1988-11-01" @default.
• W2053798825 modified "2023-09-29" @default.
• W2053798825 title "Structural Dynamics of the First Alkylidenesulfur Difluoride Oxide, OFC–CHSF ₂ O" @default.
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• W2053798825 doi "https://doi.org/10.1002/cber.19881211114" @default.
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