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• W2053802582 abstract "The reaction between Zr(C5H5)2(X)(NMe2) and ReH7(PPh3)2 results in the production of the heterometallic polyhydrides (C5H5)2Zr(X)[H6Re (PPh3)2] [(I), X = Cl; (II), X = NMe2] with the elimination of HNMe2. Both compounds were characterized spectroscopically and the structure of (I) was determined by X-ray diffraction. Compound (I) crystallizes in the orthorhombic space group P212121 with a = 12.011(4) Å, b = 10.151(3) Å, c = 33.23(1) Å and V = 4051.74 Å3. Full-matrix least squares refinement converged at R = 6.55% and Rw = 6.14%. ReH7(PPh3)2 also reacts with Zr(NMe2)4 in a 1:1 or 2:1 mole ratio to produce (NMe2)3Zr[H6Re(PPh3)2] (III) and (NMe22Zr [H6Re(PPh3)2]2 (IV) with the elimination of one or two equivalents of HNMe2, respectively. The structure of (IV) was determined by X-ray diffraction. Compound (IV) crystallizes in the monoclinic space group P21/n with a = 13.550(6) Å, b = 34.13(2) Å, c = 14.735(6) Å, β = 90.71(2)° and V = 6813.19 Å3. Full-matrix least-squares refinement converged at R = 10.4% and Rw = 9.3%. The reactivity of these compounds with simple substrates such as CO and CO2 has been surveyed and compared with that of the previously known Zr-Re polyhydride (C5H5)2Zr(H)[H6Re(PMePh2)2]." @default.
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• W2053802582 date "1989-11-01" @default.
• W2053802582 modified "2023-09-27" @default.
• W2053802582 title "Synthesis of Zr-Re-containing polyhydrides by amine elimination" @default.
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• W2053802582 doi "https://doi.org/10.1016/0304-5102(89)80169-5" @default.
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