Matches in SemOpenAlex for { <https://semopenalex.org/work/W2053842016> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2053842016 endingPage "2165" @default.
- W2053842016 startingPage "2160" @default.
- W2053842016 abstract "Spin-trapping studies of the radicals produced by photolysis of biacetyl in degassed benzene confirmed the formation of acetyl radicals as a major product and methyl radicals as a minor one. In aerated benzene, the trapped radicals are ascribed to the acetylperoxy radical yielded by the reaction of the acetyl radical and oxygen. The laser photolysis studies of biacetyl in aerated benzene containing tetramethyl-p-phenylenediamine, TMPD, demonstrate that the acetylperoxy radicals react with TMPD to give the weakly interacting complex which turns to the ion-pair complex with the rate constant 6.7 × 105 s-1. The absorption spectrum of the ion-pair complex resembles that of the cation radical of TMPD. The quantum yield for the formation of the acetylperoxy radicals produced by photolysis of biacetyl in benzene is estimated as 0.41. The addition of cyclohexene and norbornadiene is found to increase the rate for the formation of the ion-pair complex, indicating that the acetylperoxy radicals react with these olefins: the rate constants are 2.1 × 106 M-1 s-1 for cyclohexene and 1.8 × 107 M-1 s-1 for norbornadiene." @default.
- W2053842016 created "2016-06-24" @default.
- W2053842016 creator A5014822673 @default.
- W2053842016 creator A5017610382 @default.
- W2053842016 creator A5076374920 @default.
- W2053842016 creator A5083839422 @default.
- W2053842016 date "1996-01-01" @default.
- W2053842016 modified "2023-09-27" @default.
- W2053842016 title "Studies of Acetylperoxy Radicals Produced by Photolysis of Biacetyl in Aerated Benzene Solutions. Ion-Pair Formation with Tetramethyl-<i>p</i>-phenylenediamine" @default.
- W2053842016 cites W1984993672 @default.
- W2053842016 cites W1992334127 @default.
- W2053842016 cites W2004696244 @default.
- W2053842016 cites W2024921655 @default.
- W2053842016 cites W2027047635 @default.
- W2053842016 cites W2029754252 @default.
- W2053842016 cites W2032383929 @default.
- W2053842016 cites W2033289010 @default.
- W2053842016 cites W2042165603 @default.
- W2053842016 cites W2072255186 @default.
- W2053842016 cites W2077088026 @default.
- W2053842016 cites W2084033107 @default.
- W2053842016 cites W2089091958 @default.
- W2053842016 cites W2132312003 @default.
- W2053842016 cites W2334332302 @default.
- W2053842016 cites W2950989703 @default.
- W2053842016 cites W2952848703 @default.
- W2053842016 cites W4237229411 @default.
- W2053842016 doi "https://doi.org/10.1021/ja952886q" @default.
- W2053842016 hasPublicationYear "1996" @default.
- W2053842016 type Work @default.
- W2053842016 sameAs 2053842016 @default.
- W2053842016 citedByCount "8" @default.
- W2053842016 countsByYear W20538420162020 @default.
- W2053842016 countsByYear W20538420162022 @default.
- W2053842016 crossrefType "journal-article" @default.
- W2053842016 hasAuthorship W2053842016A5014822673 @default.
- W2053842016 hasAuthorship W2053842016A5017610382 @default.
- W2053842016 hasAuthorship W2053842016A5076374920 @default.
- W2053842016 hasAuthorship W2053842016A5083839422 @default.
- W2053842016 hasConcept C121332964 @default.
- W2053842016 hasConcept C139066938 @default.
- W2053842016 hasConcept C148898269 @default.
- W2053842016 hasConcept C161790260 @default.
- W2053842016 hasConcept C178790620 @default.
- W2053842016 hasConcept C185592680 @default.
- W2053842016 hasConcept C2777691172 @default.
- W2053842016 hasConcept C2779484182 @default.
- W2053842016 hasConcept C2780669175 @default.
- W2053842016 hasConcept C54582936 @default.
- W2053842016 hasConcept C62520636 @default.
- W2053842016 hasConcept C75473681 @default.
- W2053842016 hasConcept C93391505 @default.
- W2053842016 hasConceptScore W2053842016C121332964 @default.
- W2053842016 hasConceptScore W2053842016C139066938 @default.
- W2053842016 hasConceptScore W2053842016C148898269 @default.
- W2053842016 hasConceptScore W2053842016C161790260 @default.
- W2053842016 hasConceptScore W2053842016C178790620 @default.
- W2053842016 hasConceptScore W2053842016C185592680 @default.
- W2053842016 hasConceptScore W2053842016C2777691172 @default.
- W2053842016 hasConceptScore W2053842016C2779484182 @default.
- W2053842016 hasConceptScore W2053842016C2780669175 @default.
- W2053842016 hasConceptScore W2053842016C54582936 @default.
- W2053842016 hasConceptScore W2053842016C62520636 @default.
- W2053842016 hasConceptScore W2053842016C75473681 @default.
- W2053842016 hasConceptScore W2053842016C93391505 @default.
- W2053842016 hasIssue "9" @default.
- W2053842016 hasLocation W20538420161 @default.
- W2053842016 hasOpenAccess W2053842016 @default.
- W2053842016 hasPrimaryLocation W20538420161 @default.
- W2053842016 hasRelatedWork W1975504879 @default.
- W2053842016 hasRelatedWork W2039525695 @default.
- W2053842016 hasRelatedWork W2053842016 @default.
- W2053842016 hasRelatedWork W2058406139 @default.
- W2053842016 hasRelatedWork W2075844864 @default.
- W2053842016 hasRelatedWork W2080682147 @default.
- W2053842016 hasRelatedWork W2112001639 @default.
- W2053842016 hasRelatedWork W2125930836 @default.
- W2053842016 hasRelatedWork W938672060 @default.
- W2053842016 hasRelatedWork W10152710 @default.
- W2053842016 hasVolume "118" @default.
- W2053842016 isParatext "false" @default.
- W2053842016 isRetracted "false" @default.
- W2053842016 magId "2053842016" @default.
- W2053842016 workType "article" @default.