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- W2053851042 abstract "An empirical expression was derived for the actual mobility, μ, valid in an extended range of ionic strength, I, between 0.001 and 0.1 mol/l, using a three-parameter exponential fit for the ratio of actual and absolute mobilities (μ0 at I = 0), which consists of two variables: ionic strength of the buffer and charge number, z, of the solute. The charge numbers of the solute anions (21 aromatic sulfonates) ranged between 1 and 6, and the ionic strength was varied in the range mentioned using a sodium acetate buffer. The mobilities were determined at 25.0°C in a coated capillary with suppressed electroosmotic flow. The resulting fitting equation, valid under these conditions, is μ/μ0 = exp(−0.77√zI). The difference between measured mobilities and mobilities calculated from a tenfold higher or lower ionic strength, using this equation, is within 5% for all experiments. For multivalent ions, μ values can be derived from μ0 with comparable accuracy." @default.
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- W2053851042 date "1995-08-01" @default.
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- W2053851042 title "Ionic strength and charge number correction for mobilities of multivalent organic anions in capillary electrophoresis" @default.
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- W2053851042 doi "https://doi.org/10.1016/0021-9673(95)00159-k" @default.
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