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- W2053879551 abstract "Abstract Enzymatic grafting of caprolactone was carried out from poly[styrene‐ co ‐(4‐vinylbenzyl alcohol)] containing 10% hydroxyl functional monomer and compared with the grafting of vinyl acetate. A molecular weight increase due to the grafting of polycaprolactone was observed by size exclusion chromatography. Closer investigation of the grafting density by 1 H NMR revealed an upper limit to the amount of grafting of about 50–60% of the pendant hydroxyl groups leaving unreacted hydroxyl groups on the polymer backbone available for subsequent reactions. The higher grafting density (95%) obtained with vinyl acetate suggests that this is not due to limited accessibility of the backbone but sterical constrains. Moreover, the grafting action of polycaprolactone seems to be a combination of grafting from by monomer initiation and grafting onto by transesterification of polycaprolactone. magnified image" @default.
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- W2053879551 date "2007-01-30" @default.
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- W2053879551 title "Selective Enzymatic Grafting by Steric Control" @default.
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- W2053879551 doi "https://doi.org/10.1002/marc.200600575" @default.
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