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- W2053885470 abstract "Nitric oxide (NO) is a messenger molecule implicated in a number of physiological processes. Nitrosation of selenoproteins has been suggested as playing an important role in NO-mediated cellular functions such as the inactivation of glutathione peroxidase (GPx), but no chemical information about Se-nitrosated species has been available to date. Here a stable Se-nitrososelenol (RSeNO), a new class of NO derivative, was synthesized and fully characterized by X-ray crystallography and spectroscopic methods. This Se-nitrososelenol can be formed by direct transnitrosation from an S-nitrosothiol to a selenol, as is the case in the proposed mechanism for the NO-mediated inactivation of GPx." @default.
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- W2053885470 date "2004-09-25" @default.
- W2053885470 modified "2023-10-12" @default.
- W2053885470 title "Isolation of a <i>Se-</i>Nitrososelenol: A New Class of Reactive Nitrogen Species Relevant to Protein <i>Se-</i>Nitrosation" @default.
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- W2053885470 doi "https://doi.org/10.1021/ja0457009" @default.
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