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• W2053897983 abstract "Photoinduced charge separation and thermal charge recombination reactions in a series of structurally related donor−acceptor molecules based on the 4-(N-pyrrolidinyl)naphthalene-1,8-dicarboximide (5ANI) and 4-(N-piperidinyl)naphthalene-1,8-dicarboximide (6ANI) chromophores were studied in the nematic liquid crystals 4-cyano-4‘-(n-pentyl)biphenyl (5CB) and N-(4‘-methoxybenzylidene)-4-(n-butyl)aniline (MBBA) as well as in the isotropic solvents pyridine, 2-methyltetrahydrofuran, and pentyl propionate over a temperature range of 293−353 K. The photoexcited 5ANI and 6ANI chromophores donate an electron to pyromellitimide (PI), which is attached to the donors via a N−N single bond between their imide groups to give 5ANI−PI and 6ANI−PI, respectively. The photoexcited 6ANI chromophore also accepts electrons from p-methoxyaniline, which is attached to the 4-position of the naphthalene-1,8-dicarboximide as a N‘-(4‘-methoxyphenyl)piperazinyl substituent to give MeOAn−6ANI. Attachment of a secondary PI acceptor to M..." @default.
• W2053897983 created "2016-06-24" @default.
• W2053897983 creator A5072522213 @default.
• W2053897983 creator A5090580435 @default.
• W2053897983 date "2003-01-07" @default.
• W2053897983 modified "2023-09-27" @default.
• W2053897983 title "Effects of Solvent and Structural Dynamics on Electron Transfer Reactions of 4-Aminonaphthalene-1,8-dicarboximide Donor−Acceptor Molecules in Nematic Liquid Crystals and Isotropic Solvents" @default.
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• W2053897983 doi "https://doi.org/10.1021/jp021833+" @default.
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