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• W2054006590 abstract "In order to reach a better insight into the electrodeposition process of copper and cobalt, the diffusion coefficients of the electroactive species Cu+ and Co2+ are determined by radio-active tracer techniques and by chronopotentiometry. Thus, it is first possible to determine the best conditions for the application of Sand's law. However, in general case, the metal deposition creates a surface perturbation. The mathematical treatment of this phenomenon may be carried out since the exact value of the contribution of the diffusion process to the galvanostatic response is known. The influence of the surface perturbation depends on the mean path of the electroactive particles during the time of the transient pulse. It follows that, by varying the intensity of the current, the distribution of the surface accidents can be detected. Moreover, the very short time analysis of the potential gives a good insight into the nucleation process. On an inert substrate such as vitreous carbon the whole surface is available for the electronic transfer, which implies a large surface diffusion coefficient of the adatoms; an increase of this electroactive area is observed when the nuclei are growing." @default.
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• W2054006590 date "1979-03-01" @default.
• W2054006590 modified "2023-09-27" @default.
• W2054006590 title "Electrocrystallisation and diffusion process in the electroreduction of Cu+ and Co2+ ions in fused LiCl+KCl" @default.
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• W2054006590 doi "https://doi.org/10.1016/s0022-0728(79)80424-6" @default.
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