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- W2054019270 abstract "With the ferrocene imidazoline palladacycle FIP-Cl as precatalyst, quaternary N-substituted stereocenters can be generated in an asymmetric aza-Claisen rearrangement. Excellent enantioselectivities are obtained even if R and R′ have a similar or identical size (see scheme: e.g. 96 % ee for CH3/CD3)." @default.
- W2054019270 created "2016-06-24" @default.
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- W2054019270 date "2007-09-28" @default.
- W2054019270 modified "2023-10-18" @default.
- W2054019270 title "Asymmetric Formation of Allylic Amines with N-Substituted Quaternary Stereocenters by PdII-Catalyzed Aza-Claisen Rearrangements" @default.
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- W2054019270 doi "https://doi.org/10.1002/anie.200702086" @default.
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