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- W2054044474 abstract "A bistable donor-acceptor [2]catenane, which is composed of a crown ether containing a hydroquinone unit and a 1,5-diaminonaphthalene unit, interlocked mechanically by cyclobis(paraquat-p-phenylene) as its tetrachloride, exists as a mixture of translational isomers, both in the solid state and in aqueous solution. UV/vis and (1)H NMR spectroscopies demonstrate that this isomeric mixture can be switched in water in the presence of hydrochloric acid to afford a single diprotonated derivative in which only the hydroquinone unit resides inside the cavity of the tetracationic cyclophane. Treatment with 1,4-diazabicyclo[2.2.2]octane resets the molecular switch." @default.
- W2054044474 created "2016-06-24" @default.
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- W2054044474 date "2013-11-18" @default.
- W2054044474 modified "2023-09-27" @default.
- W2054044474 title "A Water-Soluble pH-Triggered Molecular Switch" @default.
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- W2054044474 doi "https://doi.org/10.1021/ja409006y" @default.
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