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- W2054045707 abstract "NiFe2−xBixO4 (x = 0, 0.1, 0.15) nanopowders were synthesized via sol–gel method. The precursor gels were calcined at 773 K in air for 1 h to obtain the pure nanostructured NiFe2−xBixO4 spinel phase. The crystal structure and magnetic properties of the substituted spinel series of NiFe2−xBixO4 have been investigated by means of 57Fe Mössbauer spectroscopy, transmission electron microscopy and alternating gradient force magnetometry. Mössbauer spectroscopic measurements revealed that Bi3+ cations tend to occupy octahedral positions in the structure of the substituted ferrite, i.e., the crystal-chemical formula of the as-prepared nanoparticles may be written as: (Fe)[NiFe1−xBix]O4 (x = 0, 0.1, 0.15), where parentheses and square brackets enclose cations on sites of tetrahedral and octahedral coordination, respectively. Selective area electron diffraction studies provided evidence that the samples of the NiFe2−xBixO4 series, independently of x, exhibit the cubic spinel structure. The values of the saturation magnetization and the coercive field of NiFe2−xBixO4 nanoparticles were found to decrease with increasing degree of bismuth substitution." @default.
- W2054045707 created "2016-06-24" @default.
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- W2054045707 date "2011-08-01" @default.
- W2054045707 modified "2023-10-02" @default.
- W2054045707 title "Structural and magnetic properties of NiFe2−xBixO4 (x=0, 0.1, 0.15) nanoparticles prepared via sol–gel method" @default.
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- W2054045707 doi "https://doi.org/10.1016/j.ceramint.2011.02.003" @default.
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