Matches in SemOpenAlex for { <https://semopenalex.org/work/W2054060951> ?p ?o ?g. }
- W2054060951 endingPage "1430" @default.
- W2054060951 startingPage "1421" @default.
- W2054060951 abstract "The phenomenon of excited state twisted intramolecular charge transfer (TICT) process in N,N-dimethylaminonaphthyl-(acrylo)-nitrile (DMANAN) has been reported on the basis of steady-state absorption and fluorescence spectroscopy in combination with quantum chemical calculations. The absorption and fluorescence characteristics of DMANAN in solvents of different polarity reveal the presence of a single species in the ground state which forms the intramolecular charge transfer state upon photoexcitation. The observed dual fluorescence is assigned to a high-energy emission from the locally excited or the Franck–Condon state and the red-shifted emission from the charge transfer (CT) state. In polar protic solvents, hydrogen-bonding interaction on CT emission has been established from the linear dependency of the position of the low-energy emission maxima on hydrogen-bonding parameter (α). The experimental findings have been correlated with the theoretical results based on TICT model obtained at density functional theory (DFT) level. The theoretical potential energy surface for the first excited state along both the donor and acceptor twist coordinates in the gas phase obtained by time dependent density functional theory (TDDFT) method and in polar solvent by time dependent density functional theory-polarized continuum model (TDDFT-PCM) method predicts well the experimental spectral properties." @default.
- W2054060951 created "2016-06-24" @default.
- W2054060951 creator A5002558069 @default.
- W2054060951 creator A5019043807 @default.
- W2054060951 creator A5034836176 @default.
- W2054060951 creator A5084679435 @default.
- W2054060951 date "2008-09-01" @default.
- W2054060951 modified "2023-09-26" @default.
- W2054060951 title "Spectroscopic and theoretical evidence for the photoinduced twisted intramolecular charge transfer state formation in N,N-dimethylaminonaphthyl-(acrylo)-nitrile" @default.
- W2054060951 cites W1538997716 @default.
- W2054060951 cites W1965865330 @default.
- W2054060951 cites W1968496644 @default.
- W2054060951 cites W1969431371 @default.
- W2054060951 cites W1969828409 @default.
- W2054060951 cites W1976556041 @default.
- W2054060951 cites W1990139741 @default.
- W2054060951 cites W1992425251 @default.
- W2054060951 cites W1995108383 @default.
- W2054060951 cites W1998287069 @default.
- W2054060951 cites W2001309031 @default.
- W2054060951 cites W2001323304 @default.
- W2054060951 cites W2003946125 @default.
- W2054060951 cites W2004696853 @default.
- W2054060951 cites W2009556953 @default.
- W2054060951 cites W2013476280 @default.
- W2054060951 cites W2017834455 @default.
- W2054060951 cites W2019249992 @default.
- W2054060951 cites W2030177217 @default.
- W2054060951 cites W2034360330 @default.
- W2054060951 cites W2042768435 @default.
- W2054060951 cites W2046124840 @default.
- W2054060951 cites W2047636811 @default.
- W2054060951 cites W2051886422 @default.
- W2054060951 cites W2055543515 @default.
- W2054060951 cites W2056444577 @default.
- W2054060951 cites W2066349788 @default.
- W2054060951 cites W2068058335 @default.
- W2054060951 cites W2075511300 @default.
- W2054060951 cites W2084678932 @default.
- W2054060951 cites W2086659534 @default.
- W2054060951 cites W2089049959 @default.
- W2054060951 cites W2090244831 @default.
- W2054060951 cites W2091255546 @default.
- W2054060951 cites W2949472289 @default.
- W2054060951 doi "https://doi.org/10.1016/j.jlumin.2008.01.015" @default.
- W2054060951 hasPublicationYear "2008" @default.
- W2054060951 type Work @default.
- W2054060951 sameAs 2054060951 @default.
- W2054060951 citedByCount "20" @default.
- W2054060951 countsByYear W20540609512012 @default.
- W2054060951 countsByYear W20540609512014 @default.
- W2054060951 countsByYear W20540609512018 @default.
- W2054060951 countsByYear W20540609512020 @default.
- W2054060951 countsByYear W20540609512022 @default.
- W2054060951 countsByYear W20540609512023 @default.
- W2054060951 crossrefType "journal-article" @default.
- W2054060951 hasAuthorship W2054060951A5002558069 @default.
- W2054060951 hasAuthorship W2054060951A5019043807 @default.
- W2054060951 hasAuthorship W2054060951A5034836176 @default.
- W2054060951 hasAuthorship W2054060951A5084679435 @default.
- W2054060951 hasConcept C112887158 @default.
- W2054060951 hasConcept C119824511 @default.
- W2054060951 hasConcept C121332964 @default.
- W2054060951 hasConcept C147597530 @default.
- W2054060951 hasConcept C152365726 @default.
- W2054060951 hasConcept C155220765 @default.
- W2054060951 hasConcept C178790620 @default.
- W2054060951 hasConcept C181500209 @default.
- W2054060951 hasConcept C184779094 @default.
- W2054060951 hasConcept C185592680 @default.
- W2054060951 hasConcept C20853536 @default.
- W2054060951 hasConcept C26873012 @default.
- W2054060951 hasConcept C2779892579 @default.
- W2054060951 hasConcept C32909587 @default.
- W2054060951 hasConcept C62520636 @default.
- W2054060951 hasConcept C71240020 @default.
- W2054060951 hasConcept C75079739 @default.
- W2054060951 hasConcept C75473681 @default.
- W2054060951 hasConceptScore W2054060951C112887158 @default.
- W2054060951 hasConceptScore W2054060951C119824511 @default.
- W2054060951 hasConceptScore W2054060951C121332964 @default.
- W2054060951 hasConceptScore W2054060951C147597530 @default.
- W2054060951 hasConceptScore W2054060951C152365726 @default.
- W2054060951 hasConceptScore W2054060951C155220765 @default.
- W2054060951 hasConceptScore W2054060951C178790620 @default.
- W2054060951 hasConceptScore W2054060951C181500209 @default.
- W2054060951 hasConceptScore W2054060951C184779094 @default.
- W2054060951 hasConceptScore W2054060951C185592680 @default.
- W2054060951 hasConceptScore W2054060951C20853536 @default.
- W2054060951 hasConceptScore W2054060951C26873012 @default.
- W2054060951 hasConceptScore W2054060951C2779892579 @default.
- W2054060951 hasConceptScore W2054060951C32909587 @default.
- W2054060951 hasConceptScore W2054060951C62520636 @default.
- W2054060951 hasConceptScore W2054060951C71240020 @default.
- W2054060951 hasConceptScore W2054060951C75079739 @default.
- W2054060951 hasConceptScore W2054060951C75473681 @default.
- W2054060951 hasIssue "9" @default.
- W2054060951 hasLocation W20540609511 @default.