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- W2054083186 abstract "The sequential nature of the unique rearrangement-dehydrogenation of cis-1-alkyl-2-aryl-3-aroylaziridines (1a-d) into 2-alkylamino-3-arylindenones (2a-d) when treated with a lithium amide has been established. Furthermore, a competitive degradation pathway has been discovered which leads to ω-aminoacetophenones and benzaldehyde, thereby accounting for the major product of this reaction. trans-1-Alkyl-2-aryl-3-aroylaziridines do not react with the lithium amides employed in these studies. Although 1-cyclohexyl-2-methyl-3-benzoylaziridine reacts with lithium amide to produce a 3-carbanion, neither a rearrangement-dehydrogenation to a 2-aminoindenone nor a more extensive degradation involving carbon-carbon bond cleavage is observed. Mechanistic pathways for these base catalyzed reactions are discussed." @default.
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- W2054083186 date "1978-12-01" @default.
- W2054083186 modified "2023-10-16" @default.
- W2054083186 title "Aziridinyl ketones. XVIII. The rearrangement-dehydrogenation of<i>cis</i>-1-cyclohexyl-2-phenyl-3-aroylaziridines" @default.
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- W2054083186 doi "https://doi.org/10.1002/jhet.5570150808" @default.
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