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• W2054168885 abstract "The reaction of (Et(3)P)(2)PtGe[N(SiMe(3))(2)](2) with dioxygen yields (Et(3)P)(2)Pt(&mgr;-eta(2)-O(2))Ge[N(SiMe(3))(2)](2) (1). Exposure of 1 to light resulted in a rearrangement to (Et(3)P)(2)PtO(2)Ge[N(SiMe(3))(2)](2) (2a), the first example of a bidentate, dianionic germanate ligand. The isomerization was judged to occur via an intramolecular O-O bond scission and rotation of the Pt-Ge bond. No free germylene was detected, and the reaction was found to be zero order. An analogue of 2a was prepared by direct reaction of (Ph(3)P)(2)PtO(2) with Ge[N(SiMe(3))(2)](2) yielding (Ph(3)P)(2)PtO(2)Ge[N(SiMe(3))(2)](2) (2b). Addition of SO(2) to 1 results in the formation of the bridging sulfate (Et(3)P)(2)Pt(&mgr;-eta(2)-SO(4))Ge[N(SiMe(3))(2)](2) (3). An infrared spectroscopy study of the sulfate reaction was performed using oxygen-18. The results indicate that direct insertion of SO(2) into the O-O bond does not occur. Formaldehyde was also observed to insert into the Pt-O bond of 1 giving (Et(3)P)(2)Pt(&mgr;-eta(2)-OCH(2)OO)Ge[N(SiMe(3))(2)](2) (5)." @default.
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• W2054168885 date "1998-11-19" @default.
• W2054168885 modified "2023-10-03" @default.
• W2054168885 title "Active Role of a Germylene Ligand in Promoting Reactions of Platinum Complexes with Oxygen and Sulfur Dioxide" @default.
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• W2054168885 doi "https://doi.org/10.1021/ic9808044" @default.
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