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• W2054170478 abstract "The use of collection efficiency measurements, at the double channel electrode, is considered in the resolution of the “classical” ECE-DISP1 problem. Particular attention is given to the case where the upstream (generator) electrode is held at a potential in the transport-limited current region, with the downstream (collector) electrode at a potential such that the initial heterogeneous electron transfer is reversed but sufficient overpotential is available to drive the second electron transfer, in the original sense, should it occur. The theory is developed for the problem, relating the collection efficiency (the ratio of transport-limited currents at the collector and generator electrodes) to the geometries of the double electrode and channel cell, the solution velocity, the homogeneous rate constant, and the nature of the mechanism operating. It is shown that under the defined conditions the two mechanisms may be readily separated, and the kinetic domain accessible to the technique is identified. The theoretical predictions are tested on the reduction of fluorescein dianion in aqueous solution (pH 9.5–10.0). Collection efficiency measurements readily point to a DISP1 assignment for this process, in agreement with previous work." @default.
• W2054170478 created "2016-06-24" @default.
• W2054170478 creator A5063156360 @default.
• W2054170478 date "1991-01-01" @default.
• W2054170478 modified "2023-10-17" @default.
• W2054170478 title "The ECE-DISP1 problem: general resolution via double channel electrode collection efficiency measurements" @default.
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• W2054170478 doi "https://doi.org/10.1016/0022-0728(91)85361-r" @default.
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