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- W2054173762 abstract "Three nickel(II), three cobalt(II) and three manganese(II) binuclear complexes have been synthesized, namely [M2(DPHA)L4](ClO4)2 [M = NiII, CoII and MnII; L = en (diaminoethane), ap (1,2-diaminopropane) and pn (1,3-diaminopropane) for NiII and CoII; L = bpy (2,2′-bipyridyl), NO2-phen (5-NO2-1,10-phenanthroline) and phen (1,10-phenanthroline) for MnII; DPHA denotes the diphenic acid dianion]. Based on IR, elemental analyses and electronic spectra, these complexes are proposed to have extented DPHA-bridged structures and consist of two nickel(II), cobalt(II) or manganese(II) in a distorted octahedral environment. The temperature dependence of magnetic susceptibilities of nickel(II) and manganese(II) complexes have been studied, giving the exchange integral J=−0.15 (en), J=−3.82 (an) and J=−2.36 cm−1 (pn) for nickel(II) complexes; J = −0.84 (bpy), J = −2.19 (NO2-phen) and J = −3.54 cm−1 (phen) for manganese(II) complexes. These indicate a weak antiferromagnetic interaction between the adjacent metal ions." @default.
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- W2054173762 date "1996-08-01" @default.
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- W2054173762 title "Novel antiferromagnetic dinuclear complexes of nickel(II), manganese(II) and cobalt(II) with diphenato as bridging ligand: Synthesis, spectra and magnetism" @default.
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- W2054173762 doi "https://doi.org/10.1016/0277-5387(95)00525-0" @default.
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