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- W2054174310 abstract "Abstract A general study on the conjugate addition of anionic nucleophiles to alkylidene bis(sulfoxides) is presented. Alkoxides gave high yielding and diastereoselective addition reactions, which could be influenced by solvents and the counteranion. Azides provided an interesting entry into sulfinyl‐substituted triazoles. Organometallics, mainly copper reagents, proved also to be valuable nucleophiles, and complete inversion of the stereoselectivity was achieved in the addition reaction with the latter. Modelizations provide a rationale for the observed diastereoselectivity." @default.
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- W2054174310 date "2011-03-11" @default.
- W2054174310 modified "2023-10-06" @default.
- W2054174310 title "Conjugate Additions to Alkylidene Bis(Sulfoxides)" @default.
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- W2054174310 doi "https://doi.org/10.1002/asia.201000904" @default.
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