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- W2054175800 abstract "Abstract Homochiral α‐(dibenzylamino) aldehydes, prepared from the corresponding α‐amino acids, react with ethynylmagnesium bromide in THF/Et 2 O at 0 °C to afford, in good yields and dr , propargylic 1,2‐amino alcohols; anti diastereomers were always formed as the major products in this reaction. These compounds are versatile intermediates in the synthesis of meso ‐ and enantiopure 1,6‐diamino‐2,5‐diols with C 2 symmetry. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
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- W2054175800 date "2006-07-12" @default.
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- W2054175800 title "Diastereoselective Ethynylation of Chiral α-(Dibenzylamino) Aldehydes: Synthesis ofmeso- and HomochiralC2-Symmetrical 1,6-Diamino-2,5-diols" @default.
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- W2054175800 doi "https://doi.org/10.1002/ejoc.200600214" @default.
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