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- W2054180010 abstract "The adsorption and reactivity of acetic acid on anatase TiO2(101) has been investigated with scanning tunneling microscopy (STM). At low coverage, acetic acid is observed to have a characteristic appearance in STM consistent with a dissociative bidentate binding geometry. At room temperature acetic acid has a relatively strong interaction with the anatase (101) surface and a near-unity sticking probability. When deposited at elevated temperatures (420 K), a saturated coverage displays a partially ordered superstructure with two domains across small regions of the anatase surface. The periodicity of these domains was found to be (2 × 1), again consistent with a bidentate binding geometry of the acetate to two neighboring Ti5c sites along the [010] direction. Heating the acetate-covered surface to 570 K in ultrahigh vacuum resulted in clean desorption of ∼90% of the molecules, leaving only a small fraction undesorbed that were mainly situated at the step edges of the anatase. STM tip pulsing of +6 V was also found to desorb acetate molecules from the surface." @default.
- W2054180010 created "2016-06-24" @default.
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- W2054180010 date "2012-05-21" @default.
- W2054180010 modified "2023-10-17" @default.
- W2054180010 title "Acetic Acid Adsorption on Anatase TiO<sub>2</sub>(101)" @default.
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- W2054180010 doi "https://doi.org/10.1021/jp303514g" @default.
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