Matches in SemOpenAlex for { <https://semopenalex.org/work/W2054183485> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2054183485 endingPage "30" @default.
- W2054183485 startingPage "30" @default.
- W2054183485 abstract "The preparation of chalcogeno metal complexes with low co-ordination numbers at the metal centres by introducing the 2,4,6-tris(trifluoromethyl)phenyl ligand (R f ) will be reported. The preparation of the chalcogenophenols R f OH, R f SH, and R f SeH is described. They are all colourless liquids which can be obtained by distillation under reduced pressure. Their reactions with the bis(trimethylsilyl)amido metal compounds M[N(SiMe 3 ) 2 ] 2 (M= Zn, Cd, Ge, Sn, Pb) lead to metal complexes of composition M(ER f ) 2 (E= O, S, Se). They are characterised by n.m.r., mass spectra, and elemental analyses. CpIn (cp = C 5 He 5 ) and TlOEt react with R f OH to afford compounds M(OR f ) 2 . In solid state both have dimeric strutures. The co-ordination number of 2 for the metal centres is shown by single crystal X-ray structure determinations. In the case of R f SH, cpIn disproportionates into indium metal and In(SR f ) 3 while TlOEt reacts to give the polymeric (TlSR f ) n 1 . All main group III metal complexes have been characterised by X-ray structure analyses." @default.
- W2054183485 created "2016-06-24" @default.
- W2054183485 creator A5041785225 @default.
- W2054183485 creator A5055058670 @default.
- W2054183485 creator A5060939320 @default.
- W2054183485 creator A5081316842 @default.
- W2054183485 date "1991-09-01" @default.
- W2054183485 modified "2023-09-27" @default.
- W2054183485 title "Preparation and characterisation of metal complexes with 2,4,6-tris(trifluoromethyl)chalcogenophenolate ligands" @default.
- W2054183485 doi "https://doi.org/10.1016/s0022-1139(00)83540-x" @default.
- W2054183485 hasPublicationYear "1991" @default.
- W2054183485 type Work @default.
- W2054183485 sameAs 2054183485 @default.
- W2054183485 citedByCount "0" @default.
- W2054183485 crossrefType "journal-article" @default.
- W2054183485 hasAuthorship W2054183485A5041785225 @default.
- W2054183485 hasAuthorship W2054183485A5055058670 @default.
- W2054183485 hasAuthorship W2054183485A5060939320 @default.
- W2054183485 hasAuthorship W2054183485A5081316842 @default.
- W2054183485 hasConcept C115624301 @default.
- W2054183485 hasConcept C116569031 @default.
- W2054183485 hasConcept C145148216 @default.
- W2054183485 hasConcept C155647269 @default.
- W2054183485 hasConcept C170493617 @default.
- W2054183485 hasConcept C178790620 @default.
- W2054183485 hasConcept C179104552 @default.
- W2054183485 hasConcept C185592680 @default.
- W2054183485 hasConcept C2776442012 @default.
- W2054183485 hasConcept C2777000832 @default.
- W2054183485 hasConcept C2780263894 @default.
- W2054183485 hasConcept C2781014771 @default.
- W2054183485 hasConcept C40325409 @default.
- W2054183485 hasConcept C543292547 @default.
- W2054183485 hasConcept C544153396 @default.
- W2054183485 hasConcept C55493867 @default.
- W2054183485 hasConcept C8010536 @default.
- W2054183485 hasConceptScore W2054183485C115624301 @default.
- W2054183485 hasConceptScore W2054183485C116569031 @default.
- W2054183485 hasConceptScore W2054183485C145148216 @default.
- W2054183485 hasConceptScore W2054183485C155647269 @default.
- W2054183485 hasConceptScore W2054183485C170493617 @default.
- W2054183485 hasConceptScore W2054183485C178790620 @default.
- W2054183485 hasConceptScore W2054183485C179104552 @default.
- W2054183485 hasConceptScore W2054183485C185592680 @default.
- W2054183485 hasConceptScore W2054183485C2776442012 @default.
- W2054183485 hasConceptScore W2054183485C2777000832 @default.
- W2054183485 hasConceptScore W2054183485C2780263894 @default.
- W2054183485 hasConceptScore W2054183485C2781014771 @default.
- W2054183485 hasConceptScore W2054183485C40325409 @default.
- W2054183485 hasConceptScore W2054183485C543292547 @default.
- W2054183485 hasConceptScore W2054183485C544153396 @default.
- W2054183485 hasConceptScore W2054183485C55493867 @default.
- W2054183485 hasConceptScore W2054183485C8010536 @default.
- W2054183485 hasIssue "1-3" @default.
- W2054183485 hasLocation W20541834851 @default.
- W2054183485 hasOpenAccess W2054183485 @default.
- W2054183485 hasPrimaryLocation W20541834851 @default.
- W2054183485 hasRelatedWork W1582008918 @default.
- W2054183485 hasRelatedWork W1966753577 @default.
- W2054183485 hasRelatedWork W1969489142 @default.
- W2054183485 hasRelatedWork W1972823246 @default.
- W2054183485 hasRelatedWork W1985872517 @default.
- W2054183485 hasRelatedWork W2008394019 @default.
- W2054183485 hasRelatedWork W2014895574 @default.
- W2054183485 hasRelatedWork W2018718103 @default.
- W2054183485 hasRelatedWork W2033915216 @default.
- W2054183485 hasRelatedWork W2033985239 @default.
- W2054183485 hasRelatedWork W2072085442 @default.
- W2054183485 hasRelatedWork W2080305418 @default.
- W2054183485 hasRelatedWork W2088987894 @default.
- W2054183485 hasRelatedWork W2118624272 @default.
- W2054183485 hasRelatedWork W2121092541 @default.
- W2054183485 hasRelatedWork W2131536047 @default.
- W2054183485 hasRelatedWork W2145835129 @default.
- W2054183485 hasRelatedWork W2313238215 @default.
- W2054183485 hasRelatedWork W2588943624 @default.
- W2054183485 hasRelatedWork W3204835027 @default.
- W2054183485 hasVolume "54" @default.
- W2054183485 isParatext "false" @default.
- W2054183485 isRetracted "false" @default.
- W2054183485 magId "2054183485" @default.
- W2054183485 workType "article" @default.