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• W2054186607 abstract "Adsorption isotherms of nitric oxide on graphitized and ungraphitized samples of carbon black (Sterling FT) and on silica (Cab-O-Sil) have been measured at 77.5 and 90.2 K. Isosteric heats of adsorption on the graphitized carbon at low coverage (θ < 0.8) are ca. 12 kJ mole−1, rising to ca. 18 kJ mole−1 at coverages above the monolayer. The results indicate absence of dimerization of adsorbed NO at low coverage. On the ungraphitized carbon the isosteric heats are close to the enthalpy of sublimation (16.6 kJ mole−1) of NO. For Cab-O-Sil, containing surface hydroxyl groups, the isosteric heats of NO show the same type of variation with surface coverage as for the graphitized carbon and are generally about 2 kJ mole−1 lower than on the carbon. There is no evidence for chemical interaction between NO and either the carbon or silica surfaces. Adsorption isotherms at 77.5 K of nitrogen, argon, carbon monoxide, krypton and oxygen have been measured on the graphitized carbon modified with preadsorbed layers of NO. For all the adsorbates except Kr, the stepwise shape of the isotherm is eliminated by the preadsorption of NO. The isotherms on the modified surface are compared with those on the bare surface by means of comparison plots (1) of amounts adsorbed at equal pressures." @default.
• W2054186607 created "2016-06-24" @default.
• W2054186607 creator A5019413210 @default.
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• W2054186607 date "1973-02-01" @default.
• W2054186607 modified "2023-09-26" @default.
• W2054186607 title "Physical adsorption of nitric oxide on graphite and silica and adsorption of gases on nitric oxide preadsorbed on carbon" @default.
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• W2054186607 doi "https://doi.org/10.1016/0021-9797(73)90297-x" @default.
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