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- W2054207631 abstract "A new 3-D vanadoborate {Na2B18V12O54(OH)6(H2O)[Na8(H2O)16]}·2H2O (1) has been hydrothermally synthesized and structurally characterized. The crystal of 1 is built up from an unusual 3-D Na–O–Na network and entrapped [V12B18O54(OH)6(H2O)]10− clusters (denoted [V12B18]). Such a Na–O–Na network is constructed by the linkage of rare 1-D helical [Na4(H2O)84+]n chains and [NaO6] octahedra. 1 represents the rare example of extended POMs with 3-D inorganic metal–oxygen networks. Magnetic measurements illustrate that 1 has antiferromagnetic exchange interactions between metal centers." @default.
- W2054207631 created "2016-06-24" @default.
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- W2054207631 date "2012-01-01" @default.
- W2054207631 modified "2023-09-26" @default.
- W2054207631 title "One novel 3-D vanadoborate with unusual 3-D Na–O–Na network" @default.
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- W2054207631 doi "https://doi.org/10.1039/c2ra21635c" @default.
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