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- W2054240706 abstract "A series of complexes has been prepared of the form [Re(dien)(PPh3)(PF3)(L)]+ (dien = diethylenetriamine), where L is an unsaturated organic molecule. The range of ligands which form η2-coordinate complexes with this metal center includes aldehydes, olefins, and dienes. In addition, thiophene, benzo[b]thiophene, and acetonitrile bind through their heteroatoms. Although {Re(dien)(PPh3)(PF3)}+ (dien = diethylenetriamine) displays chemical and spectroscopic characteristics of a potent π-base, it fails to form stable η2-coordinated complexes with aromatic molecules. However, its carbonyl analogue {Re(dien)(PPh3)(CO)}+, when combined with furan, forms the complex [Re(η2-furan)(dien)(PPh3)(CO)][OTf], a rare example of a thermally stable η2-heterocycle." @default.
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- W2054240706 date "1998-09-22" @default.
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- W2054240706 title "The Asymmetric π-Bases <i>f</i><i>ac</i>-{Re(dien)(PPh<sub>3</sub>)(PF<sub>3</sub>)}<sup>+</sup> and <i>f</i><i>ac</i>-{Re(dien)(PPh<sub>3</sub>)(CO)}<sup>+</sup>: Evidence for Formation of an η<sup>2</sup>-Furan Complex" @default.
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- W2054240706 doi "https://doi.org/10.1021/om980484w" @default.
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