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- W2054245375 abstract "By the simple hydro/solvothermal reaction, two new 3-D metal–halo cluster polymers, [NiCl2(pip)] (pip = piperazine) (1) and [Cu2I2(pip)] (2) were obtained and characterized by IR spectroscopy, CHN analysis and TG analysis. Single-crystal X-ray analysis reveals that, the 3-D network of compounds 1 and 2 are constructed from the 1-D zigzag NiCl2 chains and the 1-D castellated Cu2I2 chains bridged by pip molecules respectively. The μeff versus T curve indicates that compound 1 is ferromagnetic when T > 14 K. The photoluminscent spectrum shows that compound 2 possesses the fluorescent property with a broad emission peak at 567 nm upon excision at 397 nm." @default.
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- W2054245375 date "2009-06-01" @default.
- W2054245375 modified "2023-10-05" @default.
- W2054245375 title "Structure characterization of two new three-dimensional piperazine-bridged metal–halo coordination polymers" @default.
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- W2054245375 doi "https://doi.org/10.1016/j.ica.2008.12.025" @default.
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