Matches in SemOpenAlex for { <https://semopenalex.org/work/W2054254237> ?p ?o ?g. }
- W2054254237 endingPage "7" @default.
- W2054254237 startingPage "1" @default.
- W2054254237 abstract "Pt was synthesized within the pores of NaA zeolite and mixed with ethylbenzene (EB) chemisorbed on the acid sites in H-USY zeolite. The physical mixture was treated with D2 at 75°C, and the temperature-programmed desorption products were analyzed by mass spectrometry. The reaction of EB with spillover hydrogen results in isotopic exchange, but not in saturation of the aromatic ring. For EB adsorbed on weaker acid sites, exchange occurs primarily with the aromatic hydrogens, whereas for EB chemisorbed on stronger acid sites there is, additionally, deuterium exchange with alkyl hydrogens. Isotopic exchange by spillover hydrogen is suggested to occur only for hydrogens on the carbocations. These results for catalysis imply that the increased activity for aromatic saturation observed for metals dispersed on acidic supports is not due to the generation of new catalytic sites on the support and reaction by spillover hydrogen." @default.
- W2054254237 created "2016-06-24" @default.
- W2054254237 creator A5023735477 @default.
- W2054254237 creator A5032966947 @default.
- W2054254237 date "1998-03-01" @default.
- W2054254237 modified "2023-10-17" @default.
- W2054254237 title "Hydrogenation and deuterium exchange by spillover hydrogen of ethylbenzene adsorbed on H-USY zeolite" @default.
- W2054254237 cites W102718383 @default.
- W2054254237 cites W142305116 @default.
- W2054254237 cites W1526904473 @default.
- W2054254237 cites W1573780067 @default.
- W2054254237 cites W1596463592 @default.
- W2054254237 cites W17753482 @default.
- W2054254237 cites W1966539766 @default.
- W2054254237 cites W1971813638 @default.
- W2054254237 cites W1973836447 @default.
- W2054254237 cites W1978048393 @default.
- W2054254237 cites W1984037722 @default.
- W2054254237 cites W1994323708 @default.
- W2054254237 cites W1997807657 @default.
- W2054254237 cites W2002058323 @default.
- W2054254237 cites W2017468793 @default.
- W2054254237 cites W2028107392 @default.
- W2054254237 cites W2029382244 @default.
- W2054254237 cites W2031420656 @default.
- W2054254237 cites W2050068345 @default.
- W2054254237 cites W2056013103 @default.
- W2054254237 cites W2069111974 @default.
- W2054254237 cites W2074678003 @default.
- W2054254237 cites W2077687760 @default.
- W2054254237 cites W2085956331 @default.
- W2054254237 cites W2123685325 @default.
- W2054254237 cites W2127748823 @default.
- W2054254237 cites W25175093 @default.
- W2054254237 cites W2526354353 @default.
- W2054254237 cites W320310514 @default.
- W2054254237 cites W4211262894 @default.
- W2054254237 doi "https://doi.org/10.1016/s0926-860x(97)00337-2" @default.
- W2054254237 hasPublicationYear "1998" @default.
- W2054254237 type Work @default.
- W2054254237 sameAs 2054254237 @default.
- W2054254237 citedByCount "16" @default.
- W2054254237 countsByYear W20542542372012 @default.
- W2054254237 countsByYear W20542542372014 @default.
- W2054254237 countsByYear W20542542372015 @default.
- W2054254237 countsByYear W20542542372016 @default.
- W2054254237 countsByYear W20542542372018 @default.
- W2054254237 countsByYear W20542542372020 @default.
- W2054254237 countsByYear W20542542372022 @default.
- W2054254237 crossrefType "journal-article" @default.
- W2054254237 hasAuthorship W2054254237A5023735477 @default.
- W2054254237 hasAuthorship W2054254237A5032966947 @default.
- W2054254237 hasConcept C121332964 @default.
- W2054254237 hasConcept C150394285 @default.
- W2054254237 hasConcept C161790260 @default.
- W2054254237 hasConcept C162711632 @default.
- W2054254237 hasConcept C178790620 @default.
- W2054254237 hasConcept C179104552 @default.
- W2054254237 hasConcept C185592680 @default.
- W2054254237 hasConcept C2778077586 @default.
- W2054254237 hasConcept C2778647224 @default.
- W2054254237 hasConcept C2779533485 @default.
- W2054254237 hasConcept C2780263894 @default.
- W2054254237 hasConcept C512968161 @default.
- W2054254237 hasConcept C58364064 @default.
- W2054254237 hasConcept C62520636 @default.
- W2054254237 hasConcept C75473681 @default.
- W2054254237 hasConceptScore W2054254237C121332964 @default.
- W2054254237 hasConceptScore W2054254237C150394285 @default.
- W2054254237 hasConceptScore W2054254237C161790260 @default.
- W2054254237 hasConceptScore W2054254237C162711632 @default.
- W2054254237 hasConceptScore W2054254237C178790620 @default.
- W2054254237 hasConceptScore W2054254237C179104552 @default.
- W2054254237 hasConceptScore W2054254237C185592680 @default.
- W2054254237 hasConceptScore W2054254237C2778077586 @default.
- W2054254237 hasConceptScore W2054254237C2778647224 @default.
- W2054254237 hasConceptScore W2054254237C2779533485 @default.
- W2054254237 hasConceptScore W2054254237C2780263894 @default.
- W2054254237 hasConceptScore W2054254237C512968161 @default.
- W2054254237 hasConceptScore W2054254237C58364064 @default.
- W2054254237 hasConceptScore W2054254237C62520636 @default.
- W2054254237 hasConceptScore W2054254237C75473681 @default.
- W2054254237 hasIssue "1" @default.
- W2054254237 hasLocation W20542542371 @default.
- W2054254237 hasOpenAccess W2054254237 @default.
- W2054254237 hasPrimaryLocation W20542542371 @default.
- W2054254237 hasRelatedWork W170327244 @default.
- W2054254237 hasRelatedWork W1993724540 @default.
- W2054254237 hasRelatedWork W2003550628 @default.
- W2054254237 hasRelatedWork W2025582786 @default.
- W2054254237 hasRelatedWork W2125225652 @default.
- W2054254237 hasRelatedWork W2253301427 @default.
- W2054254237 hasRelatedWork W2361045204 @default.
- W2054254237 hasRelatedWork W2521281526 @default.
- W2054254237 hasRelatedWork W3092222317 @default.
- W2054254237 hasRelatedWork W3142009845 @default.
- W2054254237 hasVolume "168" @default.
- W2054254237 isParatext "false" @default.