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• W2054278654 abstract "The EPR spectrum of 5-doxyl stearic acid dissolved in the randomly oriented lamellar G phase of sodium decanoate, decamol, and water was recorded at room temperature and the spectral shape was analyzed using relaxation theory. The spectrum was calculated as the superposition of fast-motion spectra coming from differently oriented domains characterized by a linewidth dependent on the angle formed by the director and the magnetic field. It is shown that a quantitative interpretation of the spectral shape requires the introduction of the effect of nonquantization of the nitrogen nuclear spin along the magnetic field, the m = 0 line being especially sensitive to the inclusion of this effect. The fourth rank order parameter P4 for the spin probe was also obtained and found to be lower than the value predicted by Maier-Saupe theory on the basis of P2. A semiquantitative treatment of the polyliquid crystalline spectrum is also given providing simple explanations of the relevant spectral features." @default.
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• W2054278654 date "1981-04-01" @default.
• W2054278654 modified "2023-10-16" @default.
• W2054278654 title "The polyliquid crystalline EPR spectra of nitroxide spin probes and their interpretation" @default.
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• W2054278654 doi "https://doi.org/10.1016/0022-2364(81)90089-5" @default.
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