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• W2054289370 abstract "Abstract An efficient asymmetric synthesis of the C 22 -trihydroxy fatty acid component of macroviracin A has been developed. The key steps were highly enantioselective (i) lipase-catalyzed acylation, (ii) InCl 3 -( S )-BINOL mediated allylation, and (iii) asymmetric dihydroxylation (ADH) reaction. The moderate diastereoselectivity of the ADH reaction was overridden by converting the resultant diol diastereomers to the required epoxide enantiomer." @default.
• W2054289370 created "2016-06-24" @default.
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• W2054289370 date "2015-03-01" @default.
• W2054289370 modified "2023-09-24" @default.
• W2054289370 title "Asymmetric synthesis of the constitutive C22-carboxylic acid of macroviracin A" @default.
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• W2054289370 doi "https://doi.org/10.1016/j.tet.2015.01.010" @default.
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