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- W2054290545 abstract "The absorption spectrum of p,p′-bis-dimethylamino-azobenzene has been measured in solvents of different acidities. The bathochromic shift of the long-wave transition associated with protonation of the azo link falls in line with the corresponding shifts, observed for a series of p′-substituted p-dimethylamino-azobenzenes. The same is true – inside wider limits of error – for the pK′ values of the equilibrium: base + H⊕ ⇆ azonium-cation of these compounds. These results support the view that protonation of p,p′-bis-dimethylamino-azobenzene does not differ in principle from that of the unsymmetric p′-substituted p-dimethylaminoazobenzenes." @default.
- W2054290545 created "2016-06-24" @default.
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- W2054290545 date "1962-01-01" @default.
- W2054290545 modified "2023-09-26" @default.
- W2054290545 title "Physikalisch-chemische Eigenschaften und Elektronenstruktur der Azo-Verbindungen. Teil XI: Bemerkung zur Struktur des Azonium-Kations desp,p?-Bis-dimethylamino-azobenzols" @default.
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- W2054290545 doi "https://doi.org/10.1002/hlca.19620450108" @default.
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