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- W2054309675 abstract "AbstractSulphonation of maleated copoly (ethylen/propylen/diene), followed by its neutralisation by sodium hydroxide produces an ionomer containing both carboxylate and sulphonate anions on the backbone. Addition of zinc stearate lowers the melt viscosity of the ionomer, which is higher than the corresponding non-ionomer. Dynamic mechanical thermal analysis shows that zinc stearate acts as a low reinforcing filler under ambient conditions and as a plasticiser above 100°C (i.e. above the melting point of zinc stearate). For example, incorporation of zinc stearate causes an increase in storage modulus E′ at 25°C, but a sharp decrease in E′ at 110°C. Furthermore, the plot of tan δ v. temperature reveals that tan δ at the low glass–rubber transition temperature T g decreases, while tan δ at the high temperature ionic relaxation temperature T i increases in the presence of zinc stearate. Incorporation of carbon black lowers tan δat T g and increases tan δ at T i, thus strengthening the biphasic structure of th..." @default.
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- W2054309675 date "2001-01-01" @default.
- W2054309675 modified "2023-09-28" @default.
- W2054309675 title "Effect of zinc stearate on properties of melt processable ionomer based on sodium salt of sulphonated maleated EPDM rubber" @default.
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- W2054309675 doi "https://doi.org/10.1179/146580101101541381" @default.
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