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- W2054334138 abstract "The Soret coefficients ST of the liquids acetone, benzene, benzene-d1, 1,3,5-benzene-d3, benzene-d5, benzene-C613, benzene-d6, n-hexane, toluene, 1,2,3,4-tetrahydronaphthalene, isobutylbenzene, and 1,6-dibromohexane have been measured in protonated and perdeuterated cyclohexane by a transient holographic grating technique. It has been found that ST can be either positive or negative and even change its sign as a function of concentration. The isotope effect ΔST=−0.99×10−3K−1, which is the change of ST after isotopic substitution of cyclohexane, neither depends on concentration nor on the nature of the mixing partner. Only in the case of the polar acetone is ΔST approximately 30% larger but still concentration independent. Based on the experimental findings, some general conclusions about the dependence of the Soret coefficient on molecular properties are drawn." @default.
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- W2054334138 date "2005-07-01" @default.
- W2054334138 modified "2023-10-12" @default.
- W2054334138 title "Universal isotope effect in thermal diffusion of mixtures containing cyclohexane and cyclohexane-d12" @default.
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- W2054334138 doi "https://doi.org/10.1063/1.1948368" @default.
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